Chapter 7

Acids and Bases

Acids produce H⁺ ions in water; bases neutralise acids; soluble bases (alkalis) give OH⁻. The pH scale measures acidity.

Acids, bases and alkalis

An acid is a substance that produces hydrogen ions, H+, when dissolved in water. A base is a substance that neutralises an acid; a base that is soluble in water is called an alkali and produces hydroxide ions, OH. Common acids are hydrochloric, sulfuric and nitric acid; common alkalis are sodium hydroxide and aqueous ammonia.

Key idea

The pH scale runs from 0 to 14. pH < 7 is acidic, pH = 7 is neutral, pH > 7 is alkaline. More H+ means a lower pH.

Indicators

  • Litmus: red in acid, blue in alkali.
  • Universal indicator: shows a range of colours — red for a strong acid, green at pH 7, purple for a strong alkali.
  • Phenolphthalein: colourless in acid, pink in alkali.

Reactions of acids

Acids react in typical ways, always forming a salt:

  • acid + metal → salt + hydrogen
  • acid + base (or alkali) → salt + water (neutralisation)
  • acid + carbonate → salt + water + carbon dioxide

Worked example

Hydrochloric acid reacts with sodium hydroxide: HCl + NaOH → NaCl + H2O. The essential neutralisation is H+ + OH → H2O, forming the salt sodium chloride and water.

Remember

  • Acids give H+; alkalis give OH.
  • A strong acid is fully ionised in water; a weak acid is only partly ionised.
  • Neutralisation always makes a salt and water.

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