What is the rate of reaction?
The rate of reaction is a measure of how quickly reactants are used up or products are formed. It can be found by measuring a change over time, such as the volume of gas produced each second or the loss in mass of a flask as gas escapes.
Key idea
Average rate = amount of reactant used or product formed ÷ time taken. A steeper line on a graph means a faster rate.
Collision theory
Particles must collide with enough energy (at least the activation energy) for a reaction to happen. Anything that increases the frequency or energy of collisions increases the rate.
- Temperature ↑: particles move faster and collide more often and more energetically.
- Concentration (or pressure of a gas) ↑: more particles per unit volume, so more collisions.
- Surface area ↑ (using a powder): more particles exposed, so more collisions.
- Catalyst: provides an alternative path with a lower activation energy; it is not used up.
Worked example
A reaction produces 48 cm3 of gas in 24 s. Average rate = 48 ÷ 24 = 2 cm3/s. If the same volume were collected in only 12 s, the rate would be 48 ÷ 12 = 4 cm3/s — twice as fast.
Remember
- Higher temperature, concentration and surface area all speed up a reaction.
- A catalyst lowers the activation energy and is not consumed.
- The reaction is fastest at the start and slows as reactants are used up.