Chapter 6

Rate of Reaction

Rate of reaction measures how fast reactants form products; it increases with temperature, concentration, surface area and catalysts.

What is the rate of reaction?

The rate of reaction is a measure of how quickly reactants are used up or products are formed. It can be found by measuring a change over time, such as the volume of gas produced each second or the loss in mass of a flask as gas escapes.

Key idea

Average rate = amount of reactant used or product formed ÷ time taken. A steeper line on a graph means a faster rate.

Collision theory

Particles must collide with enough energy (at least the activation energy) for a reaction to happen. Anything that increases the frequency or energy of collisions increases the rate.

  • Temperature ↑: particles move faster and collide more often and more energetically.
  • Concentration (or pressure of a gas) ↑: more particles per unit volume, so more collisions.
  • Surface area ↑ (using a powder): more particles exposed, so more collisions.
  • Catalyst: provides an alternative path with a lower activation energy; it is not used up.

Worked example

A reaction produces 48 cm3 of gas in 24 s. Average rate = 48 ÷ 24 = 2 cm3/s. If the same volume were collected in only 12 s, the rate would be 48 ÷ 12 = 4 cm3/s — twice as fast.

Remember

  • Higher temperature, concentration and surface area all speed up a reaction.
  • A catalyst lowers the activation energy and is not consumed.
  • The reaction is fastest at the start and slows as reactants are used up.

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