Oxidation and reduction
A redox reaction is one in which oxidation and reduction happen at the same time. In terms of electrons, oxidation is loss of electrons and reduction is gain of electrons — remembered as OIL RIG (Oxidation Is Loss, Reduction Is Gain).
Key idea
Oxidation: loss of electrons / increase in oxidation number. Reduction: gain of electrons / decrease in oxidation number. The two always occur together.
Oxidising and reducing agents
An oxidising agent oxidises another substance and is itself reduced (it takes electrons). A reducing agent reduces another substance and is itself oxidised (it gives electrons).
- Acidified potassium manganate(VII) is an oxidising agent: it turns from purple to colourless when reduced.
- Potassium iodide can be oxidised to iodine, giving a brown colour.
Worked example
Zn + CuSO4 → ZnSO4 + Cu. Zinc goes from oxidation number 0 to +2 (loses 2 electrons) — it is oxidised. Copper goes from +2 to 0 (gains 2 electrons) — it is reduced. So zinc is the reducing agent and Cu2+ is the oxidising agent.
Remember
- OIL RIG: Oxidation Is Loss, Reduction Is Gain of electrons.
- The oxidising agent is itself reduced; the reducing agent is itself oxidised.
- Oxidation number rises when oxidised, falls when reduced.