Chapter 6

Redox Reactions

In redox reactions oxidation (loss of electrons) and reduction (gain of electrons) happen together — remember OIL RIG.

Oxidation and reduction

A redox reaction is one in which oxidation and reduction happen at the same time. In terms of electrons, oxidation is loss of electrons and reduction is gain of electrons — remembered as OIL RIG (Oxidation Is Loss, Reduction Is Gain).

Key idea

Oxidation: loss of electrons / increase in oxidation number. Reduction: gain of electrons / decrease in oxidation number. The two always occur together.

Oxidising and reducing agents

An oxidising agent oxidises another substance and is itself reduced (it takes electrons). A reducing agent reduces another substance and is itself oxidised (it gives electrons).

  • Acidified potassium manganate(VII) is an oxidising agent: it turns from purple to colourless when reduced.
  • Potassium iodide can be oxidised to iodine, giving a brown colour.

Worked example

Zn + CuSO4 → ZnSO4 + Cu. Zinc goes from oxidation number 0 to +2 (loses 2 electrons) — it is oxidised. Copper goes from +2 to 0 (gains 2 electrons) — it is reduced. So zinc is the reducing agent and Cu2+ is the oxidising agent.

Remember

  • OIL RIG: Oxidation Is Loss, Reduction Is Gain of electrons.
  • The oxidising agent is itself reduced; the reducing agent is itself oxidised.
  • Oxidation number rises when oxidised, falls when reduced.

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