Chapter 5

The Nuclear Atom

Protons, neutrons and electrons; proton and nucleon number; isotopes; and Rutherford's nuclear model of the atom.

Every atom has a tiny central nucleus surrounded by moving electrons. The nucleus contains protons and neutrons, together called nucleons.

Particles and charges

ParticleChargeRelative mass
Proton+11
Neutron01
Electron−1about 1/1840 (negligible)

Almost all the mass of an atom is in its nucleus. A neutral atom has equal numbers of protons and electrons.

Key idea

Proton number Z (atomic number) = number of protons, and it defines the element. Nucleon number A (mass number) = protons + neutrons. Number of neutrons = A − Z.

Isotopes and notation

Nuclide notation is written as AZX. Isotopes are atoms of the same element with the same proton number but different numbers of neutrons.

Worked example

For carbon-14, written 146C: the proton number is 6 and the nucleon number is 14. Number of neutrons = A − Z = 14 − 6 = 8.

Remember

  • Rutherford's scattering experiment showed the atom is mostly empty space with a small, dense, positive nucleus.
  • Changing the number of neutrons gives an isotope, not a new element.

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