Form 4 · Chapter 5

Ionic and Covalent Compounds

Ionic and covalent compounds differ sharply in melting point, electrical conductivity and solubility because of their different structures.

Two kinds of compound

Ionic compounds consist of a giant lattice of oppositely charged ions held by strong ionic bonds. Covalent (molecular) compounds consist of separate molecules held together only by weak intermolecular forces. These structural differences give them very different physical properties.

Comparing properties

PropertyIonicCovalent
Melting/boiling pointHighLow
State at room temp.SolidOften liquid or gas
Conducts as solidNoNo
Conducts molten/aqueousYesNo
Solubility in waterUsually solubleUsually insoluble
Solubility in organic solventInsolubleUsually soluble

Key idea / 要点

An ionic compound conducts electricity only when its ions are free to move — that is, when molten or dissolved in water. In the solid state the ions are locked in place, so it cannot conduct.

Worked example / 例题

Substance X melts at 801 °C, dissolves in water and the solution conducts electricity; it does not dissolve in tetrachloromethane. Classify X. High melting point, water-soluble, conducts when dissolved → X is an ionic compound (in fact this describes NaCl).

Remember / 记住

  • High melting point + conducts when molten/aqueous = ionic.
  • Low melting point + does not conduct = covalent.
  • "Like dissolves like": ionic in water, covalent in organic solvents.

Stuck on this topic? A verified JomKelas tutor can walk you through it.

Find a verified tutor