Two kinds of compound
Ionic compounds consist of a giant lattice of oppositely charged ions held by strong ionic bonds. Covalent (molecular) compounds consist of separate molecules held together only by weak intermolecular forces. These structural differences give them very different physical properties.
Comparing properties
| Property | Ionic | Covalent |
| Melting/boiling point | High | Low |
| State at room temp. | Solid | Often liquid or gas |
| Conducts as solid | No | No |
| Conducts molten/aqueous | Yes | No |
| Solubility in water | Usually soluble | Usually insoluble |
| Solubility in organic solvent | Insoluble | Usually soluble |
Key idea / 要点
An ionic compound conducts electricity only when its ions are free to move — that is, when molten or dissolved in water. In the solid state the ions are locked in place, so it cannot conduct.
Worked example / 例题
Substance X melts at 801 °C, dissolves in water and the solution conducts electricity; it does not dissolve in tetrachloromethane. Classify X. High melting point, water-soluble, conducts when dissolved → X is an ionic compound (in fact this describes NaCl).
Remember / 记住
- High melting point + conducts when molten/aqueous = ionic.
- Low melting point + does not conduct = covalent.
- "Like dissolves like": ionic in water, covalent in organic solvents.