Form 5 · Chapter 7

Photoelectric Effect

The photoelectric effect is the emission of electrons from a metal surface when light of high enough frequency shines on it.

What is the photoelectric effect?

When light of a high enough frequency shines on a metal surface, electrons are emitted from the metal. These emitted electrons are called photoelectrons. The effect shows that light behaves as particles (photons), not just as waves.

Key observations

  • Emission happens only if the light frequency is above a certain minimum, the threshold frequency (f₀).
  • Below f₀, no electrons are emitted no matter how bright (intense) the light is.
  • Above f₀, increasing the intensity increases the number of photoelectrons per second, but not their maximum energy.
  • Increasing the frequency increases the maximum kinetic energy of the photoelectrons.

Key formula / 关键公式

Work function (minimum energy to release an electron):
W₀ = hf₀
where h = 6.63 × 10⁻³⁴ J s and f₀ = threshold frequency.

Worked example / 例题

A metal has a threshold frequency of 6.0 × 10¹⁴ Hz. Find its work function.
W₀ = hf₀ = (6.63 × 10⁻³⁴)(6.0 × 10¹⁴) = 4.0 × 10⁻¹⁹ J.

Why waves cannot explain it

The wave theory predicts that any light, if bright enough, should eventually free electrons — but experiments show that light below f₀ never does. This "threshold" behaviour is explained only by the photon (quantum) model, where one photon gives its whole energy to one electron.

Remember / 记住

  • No emission below the threshold frequency f₀.
  • Work function W₀ = hf₀.
  • Brighter light gives more electrons; higher frequency gives faster electrons.

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